Physical Chemistry
p-ISSN: 2167-7042 e-ISSN: 2167-7069
2019; 9(1): 1-7
doi:10.5923/j.pc.20190901.01
Ethnice Dehonor Márquez1, 2, Enrique Vigueras Santiago1, Susana Hernández López2
1Laboratorio de Desarrollo y Caracterización de Materiales Avanzados (LIDMA), Facultad de Química de Química de la Universidad Autónoma del Estado de México (UAEM), Paseo Tollocan Esquina con Paseo Colón, s/n. Moderna de la Cruz, Toluca, México
2Student in the Materials Science Program, UAEM
Correspondence to: Susana Hernández López, Student in the Materials Science Program, UAEM.
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Copyright © 2019 The Author(s). Published by Scientific & Academic Publishing.
This work is licensed under the Creative Commons Attribution International License (CC BY).
http://creativecommons.org/licenses/by/4.0/
It was studied the Aluminum Trifluoromethyl Sulfonate ((Al(OTf)3) as a very effective catalyst to polymerize Epoxidized Linseed Oil (ELO) in bulk, in a very wide range of temperatures, from room temperature (25°C) to the peak temperature of the exothermal curve of polymerization. Those temperatures and times of polymerization were depending on the amount of catalyst, which was evaluated in a very wide range of loads, from 0.5 x10-3 to 70 x10-3 molar percent. As an instance, a 55 x10-3 molar percent of catalyst showed at exothermic curve from 82 to 187°C with the peak temperature at 120.3°C. This preparation allows to ELO polymerize at 25°C in 24 hrs, at 60°C in 1hr and at 80°C in 20 min and only takes 7 min to polymerize at peak temperature. The study of the opening of the epoxy ring and polymerization of ELO was made by DSC and FTIR-HART analysis. Also was evidenced by 1H-NMR that no side reactions are promoted by this catalyst at least in the first minutes of reaction.
Keywords: Aluminum triflate, Oxirane aperture, Epoxidized linseed oil
Cite this paper: Ethnice Dehonor Márquez, Enrique Vigueras Santiago, Susana Hernández López, Thermal Study of Aluminum Trifluoromethyl Sulfonate as Effective Catalyst for the Polymerization of Epoxidized Linseed Oil, Physical Chemistry, Vol. 9 No. 1, 2019, pp. 1-7. doi: 10.5923/j.pc.20190901.01.
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Figure 1. Thermograms DSC and TGA for Epoxidized Linseed Oil (ELO) |
Figure 2. Thermograms DSC and TGA for Aluminium Triflate |
Figure 3. Exhotherms from DCS curves of pure ELO and the mixtures respect to the mol percentage of catalyst |
Figure 4. Normalized FTIR-HART spectra in the range of the corresponding epoxy signal of ELO and the mixtures containing 16, 55 and 70 x 10-3 mol% of catalyst |
Figure 5. Following of the Degree of cure from isothermal experiments for (a) 5.0 x 10-4, (b) 1.0 x 10-3, (c) 2.5 x 10-3, and 5.0 x 10-3 mol% of Al(OTf)3 |
Figure 6. Cure monitoring by FT-IR in situ at 25°C for ELO + 5.0 x 10-3 % mol of Al(OTf)3 |
Figure 7. Cure monitoring by in situ FT-IR at 25°C for ELO + 5.0 x 10-3 % mol of Al(OTf)3 |
Figure 8. Cure following by in situ 1H-NMR at 40°C for ELO + 36 x 10-3 % mol of Al(OTf)3 |