American Journal of Polymer Science
p-ISSN: 2163-1344 e-ISSN: 2163-1352
2013; 3(4): 63-69
doi:10.5923/j.ajps.20130304.01
Balaram Pani1, Sidhharth Sirohi1, Dhirendra Singh2
1Bhaskaracharya College of Applied Sciences, University of Delhi, Sec-2, Phase-1, Dwarka, New Delhi, 110 075, India
2Indian Institute of Technology, Delhi-110 016, India
Correspondence to: Balaram Pani, Bhaskaracharya College of Applied Sciences, University of Delhi, Sec-2, Phase-1, Dwarka, New Delhi, 110 075, India.
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Polypropylene is a linear saturated hydrocarbon polymer. In this article, the impact of a typical fire retardant mixture of Ammonium Polyphosphate(APP) and Pentaerythritol(PER) on the fire retardant characteristics of polypropylene(PP) has been studied. The various impact of the fire retardant mixtures (APP-PER) was studied at different proportions of 3:1 and 4:1 on the PP. To observe the effect of the composition of mixtures of both (3:1 & 4:1) on PP was studied in the different mixing compositions (15%, 30% & 40%). In this experiment, the flame retardant(FR) was operated by intumescence method. The effect of various flame retardants on PP were studied by preparing a ternary mixtures of PP-APP-PER on Brabender mixture at 180C for 10 min at a speed of 80rpm. The mixture was hot pressed at 180C under10MPa pressure for 12 min to prepare sheets of suitable thickness for analysis. The prepared sheets were subjected to the laboratory test such as, Limiting Oxygen Index(LOI) and Thermogravimetric Analysis(TGA) to find out the burning behavior and changed in the weight of a specimen respectively. The flammability test was carried out to study the flame retardancy behavior of the specimen. The degradation of PP is influenced with the increase content of phosphorous in the APP-PER mixture. LOI test indicates an improvement in flame retardancy of PP due to presence of high phosphorous content in 4:1 mixture.
Keywords: Flame Retardants, Polypropylene, Ammonium Polyphosphate, Pentaerythritol, Limiting Oxygen Index
Cite this paper: Balaram Pani, Sidhharth Sirohi, Dhirendra Singh, Studies on the Effects of Various Flame Retardants on Polypropylene, American Journal of Polymer Science, Vol. 3 No. 4, 2013, pp. 63-69. doi: 10.5923/j.ajps.20130304.01.
Figure 1. Structure of Poly-Propylene |
Figure 2. Structure of Ammonium Polyphosphate |
Figure 3. Structure of Pentaerythritol |
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Figure 4. TGA curves of PP-APP-PER (APP-PER 4:1 w/w) mixture with PP at different Proportions (15%, 30%&40%) Temperatures |
Figure 5. TGA curves of PP-APP-PER(APP-PER 3:1 w/w) mixture with PP at different Proportions (15%,30%&40%) Temperatures |
Figure 6. Chemical reaction of APP and PER |